Mechanistic Aspects and Reaction Pathways for Oxidative Coupling of Methane on Mn/Na2WO4/SiO2 Catalysts
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منابع مشابه
Mechanistic Aspects and Reaction Pathways for Oxidative Coupling of Methane on Mn/Na2WO4/SiO2 Catalysts
ors that form stronger bonds with H-atoms react with lower sensitivity to the strength of the C-H bond being activated. We have previously shown that reactions with energetic H-abstractors, such as OH radicals, react less selectively with the weaker C-H bonds in HCHO (relative to stronger C-H bonds in CH4) than more stable radicals, such as O and HO2. OH radicals are among the most thermodynami...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry C
سال: 2009
ISSN: 1932-7447,1932-7455
DOI: 10.1021/jp9001302